Experimental study of multiple interior impacts

In this paper, experiments involving interior impacts on soft, lead targets are described. The term “interior impact” refers to the impact of a projectile at the bottom of a predrilled hole in the target. It is known that impact of low-velocity projectiles into such soft targets results in plastic flow and cavities similar to those obtained in high-velocity impact of hard targets. Therefore, comparatively simple rifle-propelled projectile impacts on soft targets may yield useful information for high-speed hard-target impacts. Double impacts with a short-time interval, on the order of microseconds, between projectile arrivals were conducted. The leading projectile creates a plastic flow in the target which partially seals the entrance hole. The trailing projectile must first force open the passage hole before achieving additional penetration. The total penetration was measured for different time intervals between the projectiles. A method was developed to obtain double impacts at the same point. The method utilizes a duplex round, which is made up of two separate projectiles fired from the same cartridge. With this round, a series of impact experiments was conducted. It was learned that occlusion, or the close up of the hole, is negligible for nearly simultaneous projectiles (less than 10 μs between impacts), and greatest with about 80 to 100 μs between impacts. The projectile velocity was measured by the use of properly placed photodiodes.     

Flopping phenomenon of flow behind two plates placed side-by-side normal to the flow direction

Experiments were made for the flow over two side-by-side normal plates for which the gap ratios are in the range 1.4–2.1 and the Teynolds numbers are at 6.6 × 10³ and 1.8 × 10⁴. At low gap ratios, i.e., 1.4–1.6. the gap flow appears always to be biased and flip-flops to the preferred side non-periodically with respect to time. As the gap ratio becomes larger, the percentage of time occupied by the gap flow in the biased state decreases and the non-biased state of the gap flow becomes prevalent. A comparison of the experimental results obtained under five free stream turbulence conditions further shows that the addition of artificial disturbance into the free stream promotes gap flow flopping at low gap ratios.     

On vortex shedding behind a circular disk

Abtract  Experiments were performed for individual realizations of the vortex shedding process behind a circular disk at Reynolds numbers of 10³–10⁵, at which periodic vortex shedding prevails in the wake. The phase differences regarding the individual vortex shedding structures detected at multiple circumferential locations in the wake were obtained by analyzing the hot-wire signals with a conditional-sampling scheme. The phase differences of vortex shedding detected at circumferential positions 90° apart show a wide scatter, but the anti-phase character is largely preserved in the individual vortex shedding process as detected at circumferential locations 180° apart. The randomness of phase differences involved in the vortex shedding process is noted to be essential in order to satisfy the axisymmetric property of the global flow. Received: 4 April 19969/Accepted: 29 January 1997     

High-strain-rate tests on titanium 6-6-2 utilizing a unique rate-testing machine

This paper presents the design of a unique materials-testing system capable of medium strain rates of from 10^?4 to 10²/s. The design incorporates both closed-loop hydraulic operation with that of open-loop pneumatic operation. A novel design permits accurate specimen alignment and a stiff frame which exceeds 17×10⁶ lb/in. (11.7×10⁴ MPa). The mechanine is able to perform conventional tension/compression tests, fatigue tests and, with slight modification, biaxial-stress-tube tests and triaxial-stress tests. The accurate alignment capability coupled with high frame stiffness and the pneumatic operation enables the testing of brittle materials with rigid grips. Titanium 6-6-2 was tested in both tension and compression at strain rates from 10^?4 to about 10/s at four selected temperatures. The material showed a slight strain-rate sensitivity. Yield stress was shown to increase with strain rate while ductility decreased at each test temperature.     

A Cation and Anion Dual Doping Strategy for the Elevation of Titanium Redox Potential for High-Power Sodium-Ion Batteries

Titanium-based polyanions have been intensively investigated for sodium-ion batteries owing to their superior structural stability and thermal safety. However, their low working potential hindered further applications. Now, a cation and anion dual doping strategy is used to boost the redox potential of Ti-based cathodes of Na₃Ti_0.5V_0.5(PO₃)₃N as a new cathode material for sodium ion batteries. Both the Ti³⁺/Ti⁴⁺ and V³⁺/V⁴⁺ redox couples are reversibly accessed, leading to two distinctive voltage platforms at ca. 3.3 V and ca. 3.8 V, respectively. The remarkably improved cycling stability (86.3 %, 3000 cycles) can be ascribed to the near-zero volume strain in this unusual cubic symmetry, which has been demonstrated by in situ synchrotron-based X-ray diffraction. First-principles calculations reveal its well-interconnected 3D Na diffusion pathways with low energy barriers, and the two-sodium-extracted intermediate NaTi_0.5V_0.5(PO₃)₃N is also a stable phase according to formation energy calculations.     

A practical expected-value-approach model to assess the relevant procurement costs

As an improvement to a series of expected value approach models, this study presents a supplier portfolio decision model, rather than a number of suppliers decision model. The model assesses risks as costs, considers types of heterogeneity in a procurement process and links the assessed terms in the programming model with accounting concepts. The model is then confirmed by using a procurement decision case with real data. The analysis has several implications for modelling, application and practice. In the light of the counterexamples shown, some thoughts pertaining to procurement decisions in supply management are reconsidered.     

Low temperature synthesis of titanium diboride nanosheets by molten salt–assisted borothermal reduction of TiO2

Journal of Nanoparticle Research - In this work, impact of synthesized silica nanotubes (SNTs) on morphology and performance of polyvinylidene fluoride (PVDF) nanocomposite membrane was studied....     

Mono-Heteroatom Substitution for Harnessing Excited-State Structural Planarization of Dihydrodibenzo[a,c]phenazines

With the aim of generalizing the structure–properties relationship of bending heterocyclic molecules that undergo prominent photoinduced structural planarization (PISP), a series of new dihydrodibenzo[ac]phenazine derivatives in which one nitrogen atom is replaced by oxygen ( PNO ), sulfur ( PNS ), selenium ( PNSe ), or dimethylmethanediyl ( PNC ) was strategically designed and synthesized. Compounds PNO , PNS , and PNSe have significantly nonplanar geometries in the ground state, which undergo PISP to give a planarlike conformer and hence a large emission Stokes shift. A combination of femtosecond early relaxation dynamics and computational approaches established an R*→I* (intermediate)→P* sequential kinetic pattern for PNS and PNSe , whereas PNO undergoes R*→P* one-step kinetics. The polarization ability of the substituted heteroatoms, which is in the order O<S<Se, correlates with their increase in π conjugation, and hence the Stokes shift of the emission is in the order PNO < PNS < PNSe . Compound PNSe with the largest PISP barrier was shown to be a highly sensitive viscosity probe. Further evidence for heteroatom-harnessing PISP is given by PNC , in which the dimethylmethanediyl substituent lacks lone pair electrons for π extension, showing the normal emission of the bent structure. The results led to the conclusion that PISP is ubiquitous in dihydrodibenzo[ac]phenazines, for which the driving force is elongation of the π delocalization to gain stabilization in the excited state.     

Diindeno-Fused Dibenzo[a,h]anthracene and Dibenzo[c,l]chrysene: Syntheses,Structural Analyses,and Properties

Diindeno-fused dibenzo[a,h]anthracene 6 and diindeno-fused dibenzo[c,l]chrysene 9 contain the key moieties 1,4-quinodipropene (1,4-QDP) and 2,6-naphthoquinodipropene (2,6-NQDP), respectively, and they both have an open-shell singlet ground state. The latter compound exhibits a strong biradical character and interesting properties, including a low ΔE_T−S (2.44 kcal mol⁻¹), a small HOMO–LUMO gap (1.06 eV), a wide photoabsorption range (250–1172 nm), and a large two-photon absorption cross-section (σ=1342±56 GM). This work verifies that 6 has a slightly larger HOMO–LUMO gap and ΔE_T−S than its helical isomer diindeno[2,1-f:1′,2′-j]picene (DIP), but is a much stronger two-photon absorber, verifying the important effect of geometry on the photophysical properties.     

Performance improvement of electrochromic display devices employing micro-size precipitates of tungsten oxide

In this paper, we studied the effect of micro-size WO₃ precipitates on the electrochromic characteristics based on aging test. The electrochromic mechanism can be effectively investigated by a solid-state TaN/WO₃/ITO capacitor. The experimental results reveal that WO₃ electrochromic devices with optimized aging time of 4 days exhibit a higher optical contrast and longer retention time, which is mainly attributed to the formation of micro-size WO₃ precipitates during aging process. The performance improvement using micro-size WO₃ precipitates has the potential in future large-area window or energy efficient display applications.